Tetrahedron p. 7313 - 7324 (1990)
Update date:2022-08-11
Topics:
Russell Bowman
Jackson, Stuart W.
2,6-Dinitroalkanes have been cyclised to yield vicinal dinitrocyclopentanes via stereoselective intramolecular addition of nitronate anions to α-nitroalkyl radicals. A "cyclohexane type" transition state is proposed for this radical anion cyclisation.
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