Tetrahedron Letters p. 4927 - 4930 (1988)
Update date:2022-08-10
Topics:
Scilimati, A.
Ngooi, T. K.
Sih, Charles J.
A general biocatalytic procedure for the preparation of a variety of R- and S-hydroalkanoic esters of high optical purity has been developed.The noteworthy feature of this methodology resides in the selection of a nonhydrolyzable ester at the carboxyl terminus to improve the enantiospecificity in the lipase-catalyzed hydrolysis of the acyloxy ester.
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