Journal of the American Chemical Society p. 8091 - 8095 (1993)
Update date:2022-08-17
Topics:
Inouye, Masahiko
Konishi, Takashi
Isagawa, Kakuzo
New allosteric thymine receptors, 2,6-diamidopyridine derivatives tethered to an anthracene ring by a polyoxyethylene chain, were synthesized. In these receptors, binding of 1-butylthymine was enhanced by a factor of 4-6 by recognition of sodium cations, and the changes in the electron density of the anthracene ring were found to have influence on the allosterism by through-space interaction. The anthracene-linked diamidopyridines represent a rationally designed new class of artificial allosteric receptors.
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