
Journal of the Chemical Society. Chemical communications p. 2003 - 2004 (1995)
Update date:2022-08-11
Topics:
Marciniec, Bogdan
Pietraszuk, Cezary
The reversible insertion of the vinylsilane molecule into the Ru-Si bond occurs in two different ways to give E-1,2-bis(silyl)ethene and 1,1-bis(silyl)ethene which, in combination with the previous experiments by Wakatsuki et al., provides convincing evidence for a non-metallacarbene mechanism of silylalkene disproportionation.
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