ACTIVATION OF MOLECULAR OXYGEN. SELECTIVE OXIDATION OF TERMIANL OLEFINS AND ALCOHOLS CATALYZED BY CATIONIC COMPLEXES OF RHODIUM

DOI: 10.1016/S0022-328X(00)98840-5

Source and publish data:

Journal of Organometallic Chemistry p. C8 - C10 (1983)

Update date:2022-08-16

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Authors:

Bresaan, M.

Morandini, F.

Rigo, P.

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Article abstract of DOI:10.1016/S0022-328X(00)98840-5

Rhodium(I) complexes containing hybrid "hemilabile" ligands of general formula ⁺ (R = Ph, Et, Me) are found to catalyze air oxidation of terminal olefins to the corresponding methyl ketones, of primary alcohols to acetals and of secondary alcohols to ketones.

Full text of DOI:10.1016/S0022-328X(00)98840-5

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