Oxydation catalytique de l'octene-1 en presence de complexes de rhodium(III) ou de palladium(II) associes a des acides phosphomolybdovanadiques et au dioxygene

DOI: 10.1016/0022-328X(87)80237-1

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C14 (1987)

Update date:2022-08-31

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Authors:

Ali, Bassam El

Bregeault, Jean-Marie

Martin, Jacques

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Article abstract of DOI:10.1016/0022-328X(87)80237-1

Chlororhodium(III) complexes with heteropolyacids (HPA<*>H_3+n12-nV_nO40>) catalyze the oxidation by molecular oxygen of oct-1-ene to octan-2-one in alcoholic solvents with alcohol cooxidation (T 60 deg C).The PdSO4/HPA/

Full text of DOI:10.1016/0022-328X(87)80237-1

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