Ligand-directed reaction products in the nickel-catalyzed electrochemical carboxylation of terminal alkynes

DOI: 10.1016/0022-328X(88)80330-9

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C56 (1988)

Update date:2022-08-30

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Authors:

Labbe, Eric

Dunach, Elisabet

Perichon, Jacques

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Article abstract of DOI:10.1016/0022-328X(88)80330-9

The influence of a series of N and P ligands in the nickel-catalyzed electrochemical carboxylation of 1-octyne has been studied.Different carboxylic acids are obtained depending on the nature of the ancillary ligand, and results afford an example of high ligand-directed product specificity.

Full text of DOI:10.1016/0022-328X(88)80330-9

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