Journal of Organometallic Chemistry p. 175 - 180 (1992)
Update date:2022-08-11
Topics:
Qian, Changtao
Zhu, Dunming
Li, Dongmei
Isomerization of several 1-alkenes catalyzed by organolanthanide complex/sodium hydride systems in THF at 45 deg C, affords cis- and trans-2-alkenes in excellent yields.Effects of solvent and ?-ligand of complex on this isomerization are also examined.The catalytic isomerization may occur via organolanthanide hydride intermediate.
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