Studies on organolanthanide complexes. XLI. Cata;ytic isomerization of olefins by organolanthanide complex/sodium hydride systems

DOI: 10.1016/0022-328X(92)86005-O

Source and publish data:

Journal of Organometallic Chemistry p. 175 - 180 (1992)

Update date:2022-08-11

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Authors:

Qian, Changtao

Zhu, Dunming

Li, Dongmei

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Article abstract of DOI:10.1016/0022-328X(92)86005-O

Isomerization of several 1-alkenes catalyzed by organolanthanide complex/sodium hydride systems in THF at 45 deg C, affords cis- and trans-2-alkenes in excellent yields.Effects of solvent and ?-ligand of complex on this isomerization are also examined.The catalytic isomerization may occur via organolanthanide hydride intermediate.

Full text of DOI:10.1016/0022-328X(92)86005-O

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