Excellent Aldehyde and Ketone Selectivity in Chromium(II)-Mediated Reformatsky Reactions

DOI: 10.1055/s-1997-3239

Source and publish data:

Synlett p. 731 - 733 (1997)

Update date:2022-08-11

Topics:

Authors:

Wessjohann, Ludger

Wild, Harry

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Article abstract of DOI:10.1055/s-1997-3239

The chromium Reformatsky reaction allows the highly chemoselective addition of ester enolates to aldehydes or methyl ketones at room temperature. Aldehyde selectivities of ≥ 50 : 1 vs. methyl ketones and ≥ 200 : 1 vs. larger ketones and other electrophile

Full text of DOI:10.1055/s-1997-3239

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