Chemistry Letters p. 671 - 674 (1992)
Update date:2022-08-16
Topics:
Sakata, Yasuyuki
Katayama, Yuji
Ishii, Yasutaka
Aliphatic olefins were directly converted into α-hydroxy ketones with acidic aqueous hydrogen peroxide in the presence of catalytic amount of peroxytungstophosphate (PCWP) under the biphasic system using chloroform as a solvent.The acidic medium was necessary to open the resulting epoxide to vic-diol which was subsequently oxidized to α-hydroxy ketones.
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