Tetrahedron Asymmetry p. 1741 - 1749 (1997)
Update date:2022-08-17
Topics:
Jezewski, Artur
Chajewska, Katarzyna
Wielogorski, Zbigniew
Jurczak, Janusz
The asymmetric ene reaction of N-glyoxyloyl-(2R)-bornane-10,2-sultam 2 and its hemiacetal 3 with 1-pentene 4 and 1-hexene 5 in the presence of Lewis acids is reported. All the ene reactions studied led to diastereoisomeric mixtures of olefins 6 and 7 or 8 and 9, with predominance of products of the (S) absolute configuration on the newly formed stereogenic center. The absolute configuration (via X-ray analysis of 6 and chemical correlation) and the extent of asymmetric induction were established. Stereochemical models are proposed.
View More
Tianjin SPHINX SCIENTIFIC LAB.
Contact:+86-022-66211289
Address:Tianda high-tech Park. No.80,the 4th Avenue
Yuan Shi(SuQian)Biotechnology Co.,Ltd
website:http://www.yuanshibio.com
Contact:+86-527-84226672
Address:jiangsu suqian
website:http://www.apeptides.com/en/
Contact:+86-21-60871011
Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Suzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
website:http://www.gbxfsilicones.com/
Contact:86-25-68900673
Address:He Country Provincial Fine Chemical Industrial Park of Chaohu city,Anhui province,China
Doi:10.1021/jp010909j
(2001)Doi:10.1021/ja01072a030
(1964)Doi:10.1021/ja01327a048
(1934)Doi:10.1039/c8sc02074d
(2018)Doi:10.1016/j.chembiol.2019.03.007
(2019)Doi:10.1002/cssc.201402310
(2014)
