Tetrahedron Letters p. 177 - 178 (1989)
Update date:2022-08-16
Topics:
Gouygou, M.
Tachon, C.
El Quatib, R.
Ramarijaona, O.
Etemad-Moghadam, G.
Koenig, M.
The 3,3-dihalogeno-1,2-diphosphiranes 1(a-b) and its photochemical isomers, the 2,3-dihalogeno-diphosphapropenes 8(a-b) lead to the 1,3-diphosphaallene 4 by action the methyllithium.The anionic ring opening mechanism appears most likely.
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