New chiral phosphinamide catalysts for highly enantioselective reduction of ketones

DOI: 10.1016/0040-4039(96)00404-2

Source and publish data:

Tetrahedron Letters p. 2853 - 2856 (1996)

Update date:2022-08-16

Topics:

Authors:

Gamble, Mark P.

Studley, John R.

Wills, Martin

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Article abstract of DOI:10.1016/0040-4039(96)00404-2

A novel class of recoverable and highly stable phosphinamide catalysts for the asymmetric reduction of ketones by borane is described. Enantiomeric excesses of up to 92% have been obtained using 10 mol% of the optimum catalyst.

Full text of DOI:10.1016/0040-4039(96)00404-2

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