
Tetrahedron p. 1469 - 1476 (1984)
Update date:2022-08-16
Topics:
Fristad, William E.
Peterson, John R.
Mono- and disubstituted alkenes were converted to trans-vicinal diacetates by heating with an iron(II)/persulfate/acetic acid system.The synthetic utility and limitations were identified.A mechanism for the transformation is proposed wich involves an initial addition of sulfate radical anion to the alkene followed by solvolysis, addition, hydrolysis, and acetylation.
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Doi:10.1246/bcsj.57.307
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