Tetrahedron Asymmetry p. 1919 - 1922 (1996)
Update date:2022-09-26
Topics:
Davies, Stephen G.
Ichihara, Osamu
(+)-Negamycin was synthesised employing the highly diastereoselective conjugate addition of lithium (α-methylbenzyl)benzylamide in the key step. The synthesis was completed in 13 steps starting from ethyl 4-chloroacetoacetate with an overall yield of 24%.
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