PALLADIUM-CATALYZED SYNTHESIS OF α,β-UNSATURATED KETONES FROM KETONES VIA ALLYL ENOL CARBONATES

DOI: 10.1016/S0040-4039(00)81773-6

Source and publish data:

Tetrahedron Letters p. 1797 - 1800 (1983)

Update date:2022-08-11

Topics:

Authors:

Shimizu, Isao

Minami, Ichiro

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)81773-6

Allyl enol carbonates, prepared by quenching ketone enolates with allyl chloroformate, are converted to α,β-unsaturated ketones with Pd(OAc)2-dppe catalyst in CH3CN.

Full text of DOI:10.1016/S0040-4039(00)81773-6

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