Tetrahedron Letters p. 1235 - 1238 (1984)
Update date:2022-08-16
Topics:
Pearson, Anthony J.
Chen, Yong-Shin
Hsu, Shih-Ying
Ray, Tapan
Treatment of alkenes with t-butyl hydroperoxide in the presence of Cr(CO)6 or Cr(CO)x(CH3CN)y species results in oxidation of allylic methylene groups to give α,β-unsaturated ketones, selectively in the presence of certain alcohols, and in moderate to excellent yields.
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