Cyclobutene formation accompanying an intramolecular Lewis acid-promoted spirocyclization of a propargylic silane

DOI: 10.1016/00404-0399(50)1115X-

Source and publish data:

Tetrahedron Letters p. 5499 - 5502 (1995)

Update date:2022-08-16

Topics:

Authors:

Spence, John D.

Lowrie, Lee E.

Nantz, Michael H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/00404-0399(50)1115X-

An intramolecular Lewis acid-promoted conjugate addition of a propargylic silane to a functionalized cyclohex-2-en-1-one resulted in part in the remarkable formation of a highly fused cyclobutene. The reaction was found to be dependent on the stoichiometr

Full text of DOI:10.1016/00404-0399(50)1115X-

Products guided by the article

Product name:Silane, (6-bromo-2-hexynyl)trimethyl-

Cas No:112129-48-3

R&D Labs maybe for 112129-48-3

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Wuhan HengHeDa Pharm Co., Ltd

Contact:86-27-84888681

Address:Wuhan economic & technology development zone

Relevant to this article

Doi:10.1039/j39700001380
(1970)
Synthesis and SAR studies of 1-substituted-n-(4-alkoxycarbonylpiperidin-1-yl)alkanes as potent antiarrhythmic agents

Doi:10.1016/S0960-894X(99)00456-4
(1999)
In Vitro Photodynamic Studies of a BODIPY-Based Photosensitizer

Doi:10.1002/ejoc.201601054
(2017)
Structures of allosamidins, novel insect chitinase inhibitors, produced by actinomycetes

Doi:10.1271/bbb1961.51.3251
(1987)
Doi:10.1021/jo00927a054
(1974)
Surface-Catalyzed Reaction of the Gases Hydrogen Chloride and 2-Butyne

Doi:10.1021/jo00096a058
(1994)

Article Doi