Reactions of nucleophiles with cationic bridging alkylidyne complexes

DOI: 10.1016/0022-328X(90)87243-7

Source and publish data:

Journal of Organometallic Chemistry p. 339 - 347 (1990)

Update date:2022-08-10

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Authors:

Casey, Charles P.

Vosejpka, Paul C.

Crocker, Mark

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Article abstract of DOI:10.1016/0022-328X(90)87243-7

The reaction of the μ-methylidyne complex <2(μ-CH)>⁺ PF6^- (1) with C6H5(CH3)2SiLi and CuI produced 2(μ-CO)<μ-CHSi(CH3)2C6H5> (4).Reaction of p-totyl carbyne complex <2(μ-CO)(μ-CC6H4-p-CH3)>⁺ B

Full text of DOI:10.1016/0022-328X(90)87243-7

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