Journal of Organic Chemistry p. 1198 - 1202 (1992)
Update date:2022-08-10
Topics:
Fringuelli, Francesco
Germani, Raimondo
Pizzo, Ferdinando
Santinelli, Fabio
Savelli, Gianfranco
The epoxidation of olefinic alcohol in water only has been investigated.Simple allylic alcohols are epoxidized readily and with high yields by m-chloroperbenzoic acid.Polyolefinic alcohols are epoxidized regioselectively and with excellent yields by monoperoxyphthalic acid controlling the pH of the medium.The reactions have been carried out in the presence and absence of surfactants, and their role has been investigated.
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