Bulletin of the Chemical Society of Japan p. 2348 - 2350 (1994)
Update date:2022-08-17
Topics:
Iwano, Yasunori
Kawamura, Yasuhiko
Miyoshi, Hiroki
Yoshinari, Toshifumi
Horie, Tokunaru
Photosensitized electron-transfer reactions of 3-aryl-2-methyloxaziridines gave mainly the corresponding benzaldehydes, whereas the isomeric nitrones gave imines as well as aldehydes.Deoxygenation of the nitrone occurred via the nitrone cation radical under the reaction conditions.An aryl substituent effect on the reaction and isomerizations of both cation radicals are also discussed.
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