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80
60
40
20
Conv.
Acetylation
Conv.
Alkylation
0
1st use 2nd use 3rd use 4th use
100
80
60
40
20
0
Conv.
Acetylation
Conv.
Alkylation
1st use 2nd use 3rd use 4th use
Fig. 2. Stability of Starbon®500-SO3H material (top) and ZnCl2-Starbon® (bottom) in
the two investigated processes after several uses. Reaction conditions (acetalysation):
5 mmol 5-acetyl methyl salicylate, 10 mmol acetic anhydride, 5 mL toluene, 0.1 g
catalyst, 100 °C, 3 h reaction. Reaction conditions (alkylation): 1 mmol phenol, 2 mmol
cyclohexene, 3 mL toluene, 0.2 g catalyst, 110 °C, 8 h reaction.
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