Tetrahedron p. 13039 - 13044 (1995)
Update date:2022-08-11
Topics:
Adam, Waldemar
Smerz, Alexander K.
A notably higher diastereoselectivity is observed in the dimethyldioxirane epoxidation of chiral allylic alcohols when less polar solvent mixtures are employed; this is interpreted in terms of a dipolar transition state with OH association through hydrogen bonding to the dioxirane, for which a preferential dihedral angle of >130 deg is estimated.
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