Tetrahedron p. 4395 - 4400 (1984)
Update date:2022-08-10
Topics:
Beaujean, M.
Mignani, S.
Merenyi, R.
Janousek, Z.
Viehe, H. G.
Crown ethers are dehydrodimerized in good yields when treated with ditert.-butyl peroxide in UV light.Bridged dehydrodimers of crown ethers are obtained in the presence of α-tert.-butylmercaptoacrylonitrile.Cation extraction study was performed in order to compare the binding properties of dehydrodimers vs. monomers.
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