Total synthesis of (±)-illudin M

DOI: 10.1021/jo00102a020

Source and publish data:

Journal of Organic Chemistry p. 6965 - 6967 (1994)

Update date:2022-08-11

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Authors:

Kinder Kinder

Bair Bair

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Article abstract of DOI:10.1021/jo00102a020

(+)-Illudin M (1) was synthesized in six steps starting from 1-acetyl-1-(diazoacetyl)cyclopropane (4) and 4-bromo-5,5-dimethyl-2-cyclopentenone (5). The key step of the synthesis featured a carbonyl ylide 1,3-dipolar cycloaddition reaction that was mediat

Full text of DOI:10.1021/jo00102a020

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