
Journal of Organic Chemistry p. 6965 - 6967 (1994)
Update date:2022-08-11
Topics:
Kinder
Bair
(+)-Illudin M (1) was synthesized in six steps starting from 1-acetyl-1-(diazoacetyl)cyclopropane (4) and 4-bromo-5,5-dimethyl-2-cyclopentenone (5). The key step of the synthesis featured a carbonyl ylide 1,3-dipolar cycloaddition reaction that was mediat
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