Journal of the Chemical Society. Chemical communications p. 867 - 868 (1984)
Update date:2022-08-17
Topics:
Grant, Richard D.
Rizzardo, Ezio
Solomon, David H.
In the presence of a suitable nitroxide, 2-(t-butylazo)prop-2-yl hydroperoxide (1a) decomposes cleanly into hydroxyl and t-butyl radicals; the rate constant for its disappearance in cyclohexane is given by: k = 9.58*1014 exp.(-1.47*104/T)s-1.
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