Chemistry Letters p. 1103 - 1104 (1996)
Update date:2022-08-28
Topics:
Takada, Naoki
Itoh, Shinohu
Fukuzumi, Shunichi
Electron transfer oxidation of variously 4-substituted 1-benzyl-1,4-dihydronicotinamides (RBNAH) by [Fe(phen)3]3+ (phen = 1,10-phenanthroline) results in formation of RBNAH?+, followed by cleavage of the C(4)-H or C(4)-C bond of RBNAH?+ depending on the substituent R. In particular, the C(4)-C bond cleavage of t-BuBNAH?+ yields exclusively BNA+ and tert-butyl radical (t-Bu?) which is detected by applying a rapid mixing flow electron spin resonance (ESR) technique.
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