Chemistry Letters p. 1103 - 1104 (1996)
Update date:2022-08-28
Topics:
Takada, Naoki
Itoh, Shinohu
Fukuzumi, Shunichi
Electron transfer oxidation of variously 4-substituted 1-benzyl-1,4-dihydronicotinamides (RBNAH) by [Fe(phen)3]3+ (phen = 1,10-phenanthroline) results in formation of RBNAH?+, followed by cleavage of the C(4)-H or C(4)-C bond of RBNAH?+ depending on the substituent R. In particular, the C(4)-C bond cleavage of t-BuBNAH?+ yields exclusively BNA+ and tert-butyl radical (t-Bu?) which is detected by applying a rapid mixing flow electron spin resonance (ESR) technique.
View More
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Contact:0027-717-456976
Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
Contact:+33-5-34012600
Address:28 ZA des Pignès
RongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Doi:10.1016/j.tetlet.2004.11.153
(2005)Doi:10.1039/c8nj00759d
(2018)Doi:10.1016/j.bmc.2014.07.003
(2014)Doi:10.1016/j.carbpol.2014.03.089
(2014)Doi:10.1016/S0022-1139(00)82166-1
(1977)Doi:10.1002/anie.201406907
(2014)
