Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using New Diferrocenyl Dichalcogenides (R,S)-Fe(C5H5)>2 (E = S, Se, Te), as Chiral Ligands

DOI: 10.1039/c39940001375

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1375 - 1376 (1994)

Update date:2022-08-10

Topics:

Authors:

Nishibayashi, Yoshiaki

Singh, Jai Deo

Segawa, Kyohei

Fukuzawa, Shin-ichi

Uemura, Sakae

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Article abstract of DOI:10.1039/c39940001375

The new chiral compounds, (R,S)-di<2-(1-dimethylaminoethyl)ferrocenyl> dichalcogenides (R,S)-<Fe(C5H5)>2 (E = S, Se, Te), work effectively as chiral ligands for the rhodium(I)-catalysed asymmetric hydrosilylation of alkyl aryl ketones resulting in high enantiomeric excess and moderate chemical yields.

Full text of DOI:10.1039/c39940001375

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