Convenient preparation and reaction of a divalent ytterbium thiolate

DOI: 10.1016/0040-4039(96)00591-6

Source and publish data:

Tetrahedron Letters p. 3465 - 3466 (1996)

Update date:2022-08-16

Topics:

Authors:

Taniguchi, Yuki

Nagata, Kensuke

Kitamura, Tsugio

Fujiwara, Yuzo

Deguchi, Daisuke

Maruo, Masafumi

Makioka, Yoshikazu

Takaki, Ken

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Article abstract of DOI:10.1016/0040-4039(96)00591-6

Ytterbium metal (Yb) reacts with phenylthiotrimethylsilane to generate ytterbium(II) phenylthiolate. The divalent ytterbium thiolate [Yb(SPh)₂], thus formed in situ, reacts with aromatic aldehydes to give pinacols.

Full text of DOI:10.1016/0040-4039(96)00591-6

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Product name:1,2-Ethanediol, 1,2-bis(4-chlorophenyl)-, (1R,2R)-rel-

Cas No:116262-76-1

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