Journal of the American Chemical Society p. 3596 - 3600 (1982)
Update date:2022-08-16
Topics:
Schindler, John W.
Fukuda, Robert C.
Adamson, Arthur W.
A detailed study of the non-Beer's law behavior of the absorption features of the UV spectrum of aqueous K2Pt(CN)4 and BaPt(CN)4 allows a more definitive set of excited-state assignments than previously possible for the monomer.Concentration dependence, quenching and lifetime studies of the several room-temperatuer emission features allow a distinction between fluorescences and phosphorescences and a probable assignment as to the oligomers responsible.Two excited-state absorptions and a long-lived chemical transient are found.
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