Experimental Observation of Thermally Excited Triplet States of Heavier Group 15 Element Centered Diradical Dianions

DOI: 10.1002/chem.201706060

Source and publish data:

Chemistry - A European Journal p. 3156 - 3160 (2018)

Update date:2022-07-30

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Authors:

Fang, Yong

Zhang, Li

Cheng, Cheng

Zhao, Yue

Abe, Manabu

Tan, Gengwen

Wang, Xinping

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Article abstract of DOI:10.1002/chem.201706060

One-electron reductions of Mes*As=Fl* (1; Fl=2,7-di-tert-butylfluorenylidene, Mes=2,4,6-tBu₃C₆H₂) and diarsaalkenes [1,2-b]-IF(=AsMes*)₂ (2; IF=indenofluorene) with potassium led to the isolation of the arsenic-

Full text of DOI:10.1002/chem.201706060

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