Tetrahedron Letters p. 6615 - 6618 (1989)
Update date:2022-08-26
Topics:
Barton
Halley
Ozbalik
Mehl
Oxidation of ethylbenzene, diphenylmethane and benzylcyclopropane affords, in each case, the corresponding ketone as unique product. There is no detectable attack on the aromatic rings and only traces of phenol are formed from benzene. The oxidation of cumene affords acetophenone and 2-phenyl-2-hydroxypropane in nearly the same proportions as in a Gif(IV) oxidation of cumene hydroperoxide. An explanation is given.
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