Journal of the Chemical Society. Chemical communications p. 140 - 142 (1986)
Update date:2022-08-10
Topics:
Burford, Neil
Passmore, Jack
Schriver, Melbourne J.
The radical 5-methyl-1,3,2,4-dithiadiazolyl has been prepared and isolated, and it and two new derivatives undergo essentially quantitative isomerisation to 2,3,1,4-dithiadiazolyl at room temperature: the rate of isomerisation follows second order kinetics and the mechanism is postulated to involve an unstable ?*-?* dimer intermediate.
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