Journal of Organometallic Chemistry p. 111 - 116 (1981)
Update date:2022-08-11
Topics:
Michman, M.
Nussbaum, S.
Methyltris(triphenylphosphine)cobalt catalyses the aldol condensation of acetone and ethyl methyl ketone.From acetone mesityl oxide is obtained in ca. 70percent yield, while from ethyl methyl ketone 3-methyl-2-heptene-5-one and 3-methyl-3-heptene-5-one are formed in equal amounts in a total yield of about 100percent.The latter products are known to be those of base-catalysed aldol condensation.The corresponding aldols are also observed in small quantities.The reactions mostly take place in the absence of solvent.
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