Chiral titanium complex-catalyzed carbonyl-ene reaction with glyoxylate: Remarkable positive nonlinear effect

DOI: 10.1016/0040-4020(92)80018-B

Source and publish data:

Tetrahedron p. 5671 - 5680 (1992)

Update date:2022-08-17

Topics:

Authors:

Mikami, Koichi

Terada, Masahiro

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Article abstract of DOI:10.1016/0040-4020(92)80018-B

The enantioselective glyoxylate-ene reaction catalyzed by chiral titanium complex derived from partially resolved binaphthol (BINOL) is shown to exhibit a remarkable level of asymmetric amplification (positive nonlinear effect). Thus, the optical yield of

Full text of DOI:10.1016/0040-4020(92)80018-B

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