Tetrahedron Letters p. 325 - 328 (1999)
Update date:2022-08-16
Topics:
Fukui
Fukushi
Tahara
By the use of a new axially chiral reagent, 2'-methoxy-1,1'- binaphthalene-2-carbohydroximoyl chloride (MBCC), chiral cyclic alkenes were stereoselectively derivatized into 4,5-dihydroisoxazoles. NOEs were observed between the protons of the reagent moiety and those of the alkene moiety in cycloadducts. The absolute configuration of the original alkenes was unambiguously determined by the NOE correlation.
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(1984)
