Double Asymmetric Hydrogenation of Conjugated Dienes Catalysed by Ruthenium-binap Complexes

DOI: 10.1039/c39890000769

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 769 - 770 (1989)

Update date:2022-08-11

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Authors:

Muramatsu, Hitoshi

Kawano, Hiroyuki

Ishii, Youichi

Saburi, Masahiko

Uchida, Yasuzo

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Article abstract of DOI:10.1039/c39890000769

Buta-1,3-diene-2,3-dicarboxylic acid is smoothly hydrogenated in the presence of ruthenium-(R)-binap complexes as a catalyst via two consecutive 1,2-hydrogen additions, giving rise to (S,S)-2,3-dimethylsuccinic acid with 98percent diastereoisomeric excess and 96percent enantiomeric excess.

Full text of DOI:10.1039/c39890000769

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