Mechanism of the Gif-Barton type alkane functionalization by halide and pseudohalide ions.

DOI: 10.1016/S0040-4039(00)76237-X

Source and publish data:

Tetrahedron Letters p. 1427 - 1430 (1994)

Update date:2022-08-30

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Authors:

Minisci, Francesco

Fontana, Francesca

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Article abstract of DOI:10.1016/S0040-4039(00)76237-X

The functionalization of alkanes by halide ions under the conditions of a Gif system can be explained by free-radical redox processes.The evidence is provided by trapping the intermediate alkyl radical by protonated heteroaromatic bases.

Full text of DOI:10.1016/S0040-4039(00)76237-X

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