Tetrahedron Letters p. 2727 - 2730 (1985)
Update date:2022-08-11
Topics:
Dworkin, A. S.
Brown, L. L.
Buchanan, A. C.
Smith, G. P.
Molten, anhydrous Ga2Cl6 at 100-130 deg C readily oxidizes pyrene, anthracene and naphthacene with the concomitant reduction of Ga(III) to Ga(I).Dilute solutions of these arenes (ArH) are oxidized to their radical cations (ArH+.), wich decay very slowly in Ga2Cl6, while more concentrated solutions are oxidized to stable arenium ions (ArH2+) with hydrogen derived from aryl-aryl coupling reactions.
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Doi:10.1021/ml500198b
(2015)Doi:10.1055/s-0036-1591904
(2018)Doi:10.1039/c9nj03288f
(2019)Doi:10.1016/j.tet.2008.04.029
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(2007)Doi:10.1021/ja01341a008
(1932)
