Tetrahedron p. 2005 - 2011 (1987)
Update date:2022-08-17
Topics:
Bunnelle, William H.
Randall Shangraw
The acid mediated decomposition of the Diels-A1der adduct of 1,3-cyclopentanedione with anthracene was studied. An extremely facile, acid catalyzed retro-Diels-Alder fragmentation produces 2-methylene-1,3-cyclopentanedione, which undergoes twofold electrophilic substitution on the cognate anthracene nucleus.
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Doi:10.1016/j.tetlet.2011.03.021
(2011)Doi:10.1007/BF00568641
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(2006)Doi:10.1021/ja01157a023
(1950)Doi:10.1002/anie.201602602
(2016)Doi:10.1007/s10989-017-9581-9
(2017)
