Chemistry Letters p. 531 - 534 (1994)
Update date:2022-08-11
Topics:
Onozawa, Shun-ya
Sakakura, Toshiyasu
Tanaka, Masato
A wide variety of aldehydes are efficiently dimerized to esters by a catalytic amount of (C5Me5)2LnCH(SiMe3)2 (Ln=Nd, La).The reaction is applicable to the synthesis of polyesters from dialdehydes.A stoichiometric reaction of the lanthanum complex with benzaldehyde indicates the intermediacy of alkoxo complexes in the catalysis.
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