Tetrahedron Letters p. 6917 - 6920 (1988)
Update date:2022-08-11
Topics:
Ochiai, Masahito
Inenaga, Minako
Nagao, Yoshimitsu
Moriarty, Robert M.
Vaid, Radhe K.
Duncan, Michael P.
Cyclic amino acids L-proline, pipecolinic acid and L-2-pyrrolidinone-5-carboxylic acid undergo oxidative decarboxylation with iodosobenzene in various solvents (including water) to yield the lactam and imide in the latter case.The reaction proceeds via initial imine formation.
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