Tetrahedron Letters p. 3057 - 3060 (1992)
Update date:2022-08-30
Topics:
Coppa, Fausta
Fontana, Francesca
Lazzarini, Edoardo
Minisci, Francesco
Pianese, Guiseppe
Zhao, Lihua
Methoxy- and ethoxycarbonyl radicals were easily produced by silver-catalyzed decarboxylation of methyl and ethyl esters of oxalic acid by S2O8(2-).They were utilized for the alkoxycarbonylation of heteroaromatic bases with high yield and selectivity in a two-phase system, suitable for practical applications.
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