STEREOCHEMISTRY OF β-HYDROXYDODECANOYL THIOESTER DEHYDRATION CATALYZED BY FATTY ACID SYNTHETASE FROM BREVIBACTERIUM AMMONIAGENES

DOI: 10.1016/S0040-4039(00)87191-9

Source and publish data:

Tetrahedron Letters p. 1689 - 1692 (1982)

Update date:2022-08-17

Topics:

Authors:

Saito, Kazuki

Kawaguchi, Akihiko

Seyama, Yousuke

Yamakawa, Tamio

Okuda, Shigenobu

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Article abstract of DOI:10.1016/S0040-4039(00)87191-9

The pro-4S hydrogen of trans-α,β-dodecenoyl thioester was abstracted and a proton was added to the 2-Si face during the prototropic isomerization catalyzed by β-hydroxydodecenoyl thioester dehydrase.

Full text of DOI:10.1016/S0040-4039(00)87191-9

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