The Reality of Polar Transition States in Photobromination of Toluenes by N-Bromosuccinimide (NBS)

DOI: 10.1021/ja00300a026

Source and publish data:

Journal of the American Chemical Society p. 4234 - 4237 (1985)

Update date:2022-08-17

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Authors:

Kim, Sung Soo

Choi, Seung Yong

Kang, Chul Hyun

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Article abstract of DOI:10.1021/ja00300a026

Relative reactivities of toluene and substituted toluenes toward NBS have been compared in CCl4 (heterogeneous phase) and in CH2Cl2 (homogeneous phase).Hammett correlations show better fit with ?⁺ to give ρ's as follows, ρ=-1.41 (-1.41), -1.33,

Full text of DOI:10.1021/ja00300a026

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