Inorganic Chemistry
Article
E. Electrocatalytic and Photocatalytic Hydrogen Production from
Acidic and Neutral-pH Aqueous Solutions Using Iron Phosphide
Nanoparticles. ACS Nano 2014, 8 (11), 11101−11107.
(59) Li, D.; Senevirathne, K.; Aquilina, L.; Brock, S. L. Effect of
Synthetic Levers on Nickel Phosphide Nanoparticle Formation:
Ni5P4 and NiP2. Inorg. Chem. 2015, 54 (16), 7968−75.
(
41) Popczun, E. J.; Read, C. G.; Roske, C. W.; Lewis, N. S.; Schaak,
(60) Fu, Q.; Wu, T.; Fu, G.; Gao, T.; Han, J.; Yao, T.; Zhang, Y.;
Zhong, W.; Wang, X.; Song, B. Skutterudite-Type Ternary Co1−
xNixP3 Nanoneedle Array Electrocatalysts for Enhanced Hydrogen
and Oxygen Evolution. ACS Energy Lett. 2018, 3 (7), 1744−1752.
(61) Wang, K. W.; She, X. L.; Chen, S.; Liu, H. L.; Li, D. H.; Wang,
Y.; Zhang, H. W.; Yang, D. J.; Yao, X. D. Boosting hydrogen evolution
via optimized hydrogen adsorption at the interface of CoP3 and Ni2P.
J. Mater. Chem. A 2018, 6 (14), 5560−5565.
R. E. Highly active electrocatalysis of the hydrogen evolution reaction
by cobalt phosphide nanoparticles. Angew. Chem., Int. Ed. 2014, 53
(
21), 5427−30.
(
42) McEnaney, J. M.; Crompton, J. C.; Callejas, J. F.; Popczun, E.
J.; Biacchi, A. J.; Lewis, N. S.; Schaak, R. E. Amorphous Molybdenum
Phosphide Nanoparticles for Electrocatalytic Hydrogen Evolution.
Chem. Mater. 2014, 26 (16), 4826−4831.
(62) Wu, T.; Pi, M.; Wang, X.; Zhang, D.; Chen, S. Three-
(43) Jiang, J.; Wang, C. D.; Zhang, J. J.; Wang, W. L.; Zhou, X. L.;
dimensional metal-organic framework derived porous CoP3 concave
polyhedrons as superior bifunctional electrocatalysts for the evolution
of hydrogen and oxygen. Phys. Chem. Chem. Phys. 2017, 19 (3),
Pan, B. C.; Tang, K. B.; Zuo, J.; Yang, Q. Synthesis of FeP2/C
nanohybrids and their performance for hydrogen evolution reaction. J.
Mater. Chem. A 2015, 3 (2), 499−503.
2
(
104−2110.
(
44) Dahl, E.; Hazell, R. G.; Rasmussen, S. E.; Heinegård, D.;
63) Kanatzidis, M. G.; Pottgen, R.; Jeitschko, W. The metal flux: a
̈
Balaban, A. T.; Craig, J. C. Refined Crystal Structures of PtP2 and
preparative tool for the exploration of intermetallic compounds.
FeP2. Acta Chem. Scand. 1969, 23, 2677−2684.
Angew. Chem., Int. Ed. 2005, 44 (43), 6996−7023.
(
45) Boda, G.; Stenstrom, B.; Sagredo, V.; Beckman, O.; Carlsson,
̈
(64) Harris, D. C. Quantitative Chemical Analysis; W. H. Freeman
B.; Rundqvist, S. Magnetic and Electric Properties of FeP 2 Single
and Co.: New York, 1982.
65) Olofsson, O.; Aava, U.; Haaland, A.; Resser, D.; Rasmussen, S.
Crystals. Phys. Scr. 1971, 4 (3), 132−134.
(
(46) Lee, C. H.; Kito, H.; Ihara, H.; Akita, K.; Yanase, N.; Sekine, C.;
E.; Sunde, E.; Sørensen, N. A. X-Ray Investigations of the Tin-
Shirotani, I. Single crystal growth of skutterudite CoP3 under high
Phosphorus System. Acta Chem. Scand. 1970, 24, 1153−1162.
pressure. J. Cryst. Growth 2004, 263 (1−4), 358−362.
(66) Ritscher, A.; Schmetterer, C.; Ipser, H. Pressure dependence of
(47) Jeitschko, W.; Foecker, A. J.; Paschke, D.; Dewalsky, M. V.;
the tin−phosphorus phase diagram. Monatsh. Chem. 2012, 143 (12),
593−1602.
67) Okamoto, H. P-Sn (Phosphorus-Tin). J. Phase Equilib. 1993, 14
2), 263−264.
68) Gao, M. R.; Zheng, Y. R.; Jiang, J.; Yu, S. H. Pyrite-Type
Nanomaterials for Advanced Electrocatalysis. Acc. Chem. Res. 2017, 50
9), 2194−2204.
69) Son, C. Y.; Kwak, I. H.; Lim, Y. R.; Park, J. FeP and FeP2
Evers, C. B. H.; Kunnen, B.; Lang, A.; Kotzyba, G.; Rodewald, U. C.;
Moller, M. H. Crystal structure and properties of some filled and
unfilled skutterudites: GdFe4P12, SmFe4P12, NdFe4As12, Eu0.54-
Co4Sb12, Fe0.5Ni0.5P3, CoP3, and NiP3. Z. Anorg. Allg. Chem. 2000,
1
(
(
(
6
(
26 (5), 1112−1120.
48) Kloc, C.; Luxsteiner, M. C.; Keil, M.; Baumann, J. R.; Doll, G.;
(
Bucher, E. Growth and Characterization of Cup2 Single-Crystals. J.
Cryst. Growth 1990, 106 (4), 635−642.
(
nanowires for efficient electrocatalytic hydrogen evolution reaction.
(49) Odile, J. P.; Soled, S.; Castro, C. A.; Wold, A. Crystal growth
Chem. Commun. 2016, 52 (13), 2819−22.
and characterization of the transition-metal phosphides copper
diphosphide, nickel diphosphide, and rhodium triphosphide. Inorg.
Chem. 1978, 17 (2), 283−286.
(70) Schipper, D. E.; Zhao, Z. H.; Thirumalai, H.; Leitner, A. P.;
Donaldson, S. L.; Kumar, A.; Qin, F.; Wang, Z. M.; Grabow, L. C.;
Bao, J. M.; Whitmire, K. H. Effects of Catalyst Phase on the Hydrogen
Evolution Reaction of Water Splitting: Preparation of Phase-Pure
Films of FeP, Fe2P, and Fe3P and Their Relative Catalytic Activities.
Chem. Mater. 2018, 30 (10), 3588−3598.
(50) Donohue, P. C.; Bither, T. A.; Young, H. S. High-pressure
synthesis of pyrite-type nickel diphosphide and nickel diarsenide.
Inorg. Chem. 1968, 7 (5), 998−1001.
(51) Barry, B. M.; Gillan, E. G. A General and Flexible Synthesis of
(71) Tian, J.; Liu, Q.; Liang, Y.; Xing, Z.; Asiri, A. M.; Sun, X. FeP
Transition-Metal Polyphosphides via PCl3 Elimination. Chem. Mater.
009, 21 (19), 4454−4461.
nanoparticles film grown on carbon cloth: an ultrahighly active 3D
hydrogen evolution cathode in both acidic and neutral solutions. ACS
Appl. Mater. Interfaces 2014, 6 (23), 20579−84.
2
(
52) Kraus, W.; Nolze, G. POWDER CELL − a program for the
representation and manipulation of crystal structures and calculation
(72) Wang, J. M.; Liu, Z.; Zheng, Y. W.; Cui, L.; Yang, W. R.; Liu, J.
of the resulting X-ray powder patterns. J. Appl. Crystallogr. 1996, 29
Q. Recent advances in cobalt phosphide based materials for energy-
(
3), 301−303.
related applications. J. Mater. Chem. A 2017, 5 (44), 22913−22932.
(
53) Almeida, C. M. V. B.; Giannetti, B. F. A new and practical
(73) Shinagawa, T.; Garcia-Esparza, A. T.; Takanabe, K. Insight on
carbon paste electrode for insoluble and ground samples. Electrochem.
Commun. 2002, 4 (12), 985−988.
Tafel slopes from a microkinetic analysis of aqueous electrocatalysis
for energy conversion. Sci. Rep. 2015, 5, 13801.
(54) Sauber, M.; Dixon, D. G. Electrochemical study of leached
(
74) Fang, Y. H.; Liu, Z. P. Tafel Kinetics of Electrocatalytic
Reactions: From Experiment to First-Principles. ACS Catal. 2014, 4
12), 4364−4376.
75) Hu, J.; Zheng, S. L.; Zhao, X.; Yao, X.; Chen, Z. A theoretical
chalcopyrite using solid paraffin-based carbon paste electrodes.
Hydrometallurgy 2011, 110 (1−4), 1−12.
(
(55) Anantharaj, S.; Ede, S. R.; Karthick, K.; Sam Sankar, S.;
(
Sangeetha, K.; Karthik, P. E.; Kundu, S. Precision and correctness in
the evaluation of electrocatalytic water splitting: revisiting activity
parameters with a critical assessment. Energy Environ. Sci. 2018, 11
study on the surface and interfacial properties of Ni3P for the
hydrogen evolution reaction. J. Mater. Chem. A 2018, 6 (17), 7827−
7834.
(76) Tian, J.; Liu, Q.; Cheng, N.; Asiri, A. M.; Sun, X. Self-supported
Cu3P nanowire arrays as an integrated high-performance three-
dimensional cathode for generating hydrogen from water. Angew.
Chem., Int. Ed. 2014, 53 (36), 9577−81.
(77) Read, C. G.; Callejas, J. F.; Holder, C. F.; Schaak, R. E. General
Strategy for the Synthesis of Transition Metal Phosphide Films for
Electrocatalytic Hydrogen and Oxygen Evolution. ACS Appl. Mater.
Interfaces 2016, 8 (20), 12798−803.
(78) Burdett, J. K.; Coddens, B. A. Geometrical-electronic
relationships in the series palladium diphosphide, palladium
(
4), 744−771.
(
56) Chen, Z.; Dinh, H. N.; Miller, E. Photoelectrochemical Water
Splitting: Standards, Experimental Methods, and Protocols; Springer:
New York, NY, 2013.
(57) McCrory, C. C.; Jung, S.; Peters, J. C.; Jaramillo, T. F.
Benchmarking heterogeneous electrocatalysts for the oxygen
evolution reaction. J. Am. Chem. Soc. 2013, 135 (45), 16977−87.
(58) Jiang, P.; Liu, Q.; Sun, X. NiP(2) nanosheet arrays supported
on carbon cloth: an efficient 3D hydrogen evolution cathode in both
acidic and alkaline solutions. Nanoscale 2014, 6 (22), 13440−5.
K
Inorg. Chem. XXXX, XXX, XXX−XXX