Theoretical and experimental studies of the flash pyrolysis of trimethylsilyl azide and trimethylgermyl azide: Generation and He I photoelectron spectra of iminosilylene and iminogermylene

DOI: 10.1021/om00150a003

Source and publish data:

Organometallics p. 1387 - 1392 (1987)

Update date:2022-08-18

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Authors:

Guimon, Claude

Pfister-Guillouzo, Geneviève

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Article abstract of DOI:10.1021/om00150a003

The generation and the detection of iminosilylene and its germanium analogue from trimethylsilyl (and germyl) azide by gas-phase flash pyrolysis (1100 K, 10^-2 mbar) are described. The ab initio study of molecular rearrangements of the (CH₃

Full text of DOI:10.1021/om00150a003

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