Chiral catalysts for enantioselective intermolecular cyclopropanation reactions with methyl phenyldiazoacetate. Origin of the solvent effect in reactions catalyzed by homochiral dirhodium(II) prolinates

DOI: 10.1016/0040-4039(96)00822-2

Source and publish data:

Tetrahedron Letters p. 4129 - 4132 (1996)

Update date:2022-08-29

Topics:

Authors:

Doyle, Michael P.

Zhou, Qi-Lin

Charnsangavej, Chutaporn

Longoria, Mario A.

McKervey, M. Anthony

Garcia, Concepcion Fernandez

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Article abstract of DOI:10.1016/0040-4039(96)00822-2

The highest levels of enantiocontrol in intermolecular cyclopropanation reactions of methyl phenyldiazoacetate have been achieved with homochiral dirhodium(II) prolinates in pentane, the solvent effect for which (0.8 ± 0.2 kcal/mol) is associated with lig

Full text of DOI:10.1016/0040-4039(96)00822-2

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