Bulletin of the Chemical Society of Japan p. 2407 - 2410 (1983)
Update date:2022-08-17
Topics:
Wang
Hattori
Tanabe
The acid-base properties of ZrO//2-SnO//2 with different compositions have been measured by the indicator method and the adsorption with NH//3 and CO//2 and the catalytic activities studied. The ZrO//2-SnO//2 (atomic ratio equals 9:1) catalyst which was found to have the highest acid strength and the maximum acid amount exhibited the highest activities for the isomerization of cyclopropane and the dehydration of 2-butanol. The activities of the catalysts with different compositions for the two reactions correlated with the acidic properties. On the other hand, the activities for the isomerization of 1-butene and the decomposition of diacetone alcohol (4-hydroxyl-4-methyl-2-pentanone) correlated with the basic properties. The activity for the dehydrogenation of 2-butanol was found to increase with an increase of the SnO//2 content. The active sites on the ZrO//2-SnO//2 catalysts are discussed.
View MoreQingdao Pana-Life Biochem Co.,Ltd.
Contact:86-532-87683902
Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Shanghai better-in Medical Technology Co.,LTD.
Contact:+86-21-38921049
Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Neworld Chemical Co., Ltd Shanghai
Contact:+86-21-62202658
Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Jiangsu Chunjiang AgroChemical Co.,Ltd.
Contact:+86-13817348163
Address:Panjiawan 84, Zhixi Town, Jintan City, China
website:http://www.antimex.com
Contact:0086-21-50563169
Address:Room1027,No.Jinyu Road,Pudong
Doi:10.1039/c1jm13229f
(2011)Doi:10.1021/jo0014764
(2001)Doi:10.1039/d0gc03861j
(2021)Doi:10.1021/acs.jmedchem.6b00040
(2016)Doi:10.1016/j.molcata.2010.10.026
(2011)Doi:10.1002/jhet.5570420540
(2005)