Pyrolysis of Bicycloheptane-2-thiols: Evidence for a Carbene Intermediate in a Thermal Hydrogen Sulphide Elimination

DOI: 10.1039/c39870000416

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 416 - 417 (1987)

Update date:2022-08-30

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Authors:

Johnson, Douglas E.

Dimian, Adel F.

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Article abstract of DOI:10.1039/c39870000416

Pyrolysis of endo- and exo-bicyclo<2.2.1>heptane-2-thiols yields tricyclo<2.2.1.0^2,6>heptane and bicyclo<2.2.1>hept-2-ene via competing carbene and radical mechanisms.

Full text of DOI:10.1039/c39870000416

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