Pyrolysis of Bicycloheptane-2-thiols: Evidence for a Carbene Intermediate in a Thermal Hydrogen Sulphide Elimination

DOI: 10.1039/c39870000416

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 416 - 417 (1987)

Update date:2022-08-30

Topics:

Authors:

Johnson, Douglas E.

Dimian, Adel F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870000416

Pyrolysis of endo- and exo-bicyclo<2.2.1>heptane-2-thiols yields tricyclo<2.2.1.0^2,6>heptane and bicyclo<2.2.1>hept-2-ene via competing carbene and radical mechanisms.

Full text of DOI:10.1039/c39870000416

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,5-Norbornadiene

Cas No:121-46-0

R&D Labs maybe for 121-46-0

Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.
Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China

Relevant to this article

Preparation of 2(3H)-benzimidazolone and its derivative under aqueous condition as a potential agent for antidiabetic compounds

Doi:10.14233/ajchem.2013.13372
(2013)
Identification of (Z)-3:(E)-2-Hexenal isomerases essential to the production of the leaf aldehyde in plants

Doi:10.1074/jbc.M116.726687
(2016)
Lipophilic phenolic antioxidants: Correlation between antioxidant profile, partition coefficients and redox properties

Doi:10.1016/j.bmc.2010.06.090
(2010)
Reaction of Organyltrifluorosilanes with Dimethylsulfoxide and Dimethylformamide and Its Spectroscopic Investigation

Doi:10.1023/A:1014271706096
()
The first supported N-pyridinyl proline-derived chiral catalyst for the kinetic resolution of racemic alcohols

Doi:10.1055/s-2003-38354
(2003)
The oxa-di-π-methane rearrangement of β,γ-unsaturated aldehydes

Doi:10.1016/0040-4039(94)02402-W
(1995)

Article Doi